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No, if I remember correctly you can get Lunala by going back to that bridge from the very beginning of the game, the one where you save Nebby from the Spearow.
Edit: Wait that might be post-game only.
You can catch Lunala before the Elite Four. After you defeat Gladion outside Mount Lanakila, he mentions that he saw Lillie heading to Mahalo Trail (where the bridge is) with something on her mind. Then you can go and find her there, and challenge Nebby to a battle.